Friday, July 4, 2014

ELECTROCHEMISTRY EAMCET MCQ’S
1. The difference between the electrode potentials of two electrodes when no
current is drawn through the cell is called ___________.
(i) Cell potential
(ii) Cell emf
(iii) Potential difference
(iv) Cell voltage
2. Which of the following statement is not correct about an inert electrode in a
cell?
(i) It does not participate in the cell reaction.
(ii) It provides surface either for oxidation or for reduction reaction.
(iii) It provides surface for conduction of electrons.
(iv) It provides surface for redox reaction.
3. Which of the statements about solutions of electrolytes is not correct?
(i) Conductivity of solution depends upon size of ions.
(ii) Conductivity depends upon viscosiy of solution.
(iii) Conductivity does not depend upon solvation of ions present in solution.
(iv) Conductivity of solution increases with temperature.
 4. The cell constant of a conductivity cell _____________.
(i) changes with change of electrolyte.
(ii) changes with change of concentration of electrolyte.
(iii) changes with temperature of electrolyte.
(iv) remains constant for a cell.
5. While charging the lead storage battery ______________.
(i) PbSO4 anode is reduced to Pb.
(ii) PbSO4 cathode is reduced to Pb
(iii) PbSO4 cathode is oxidised to Pb.
(iv) PbSO4 anode is oxidised to PbO2.
6. Use the data given in Q.8 and find out the most stable ion in its reduced form.
(i) Cl–
(ii) Cr3+
(iii) Cr
(iv) Mn2+
 7. Use the data given in Q.8 and find out which of the following is the strongest
oxidising agent.
(i) Cl–
(ii) Mn2+
(iii) MnO4–

(iv) Cr3+
SOLutions EAMCET MCQ’S
1. Which of the following units is useful in relating concentration of solution
with its vapour pressure?
(i) mole fraction
(ii) parts per million
(iii) mass percentage
(iv) molality
2. On dissolving sugar in water at room temperature solution feels cool to touch.
Under which of the following cases dissolution of sugar will be most rapid?
(i) Sugar crystals in cold water.
(ii) Sugar crystals in hot water.
(iii) Powdered sugar in cold water.
(iv) Powdered sugar in hot water.
3. At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent
is __________.
(i) less than the rate of crystallisation
(ii) greater than the rate of crystallisation
(iii) equal to the rate of crystallisation
(iv) zero
4. A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’
takes place when small amount of ‘A’ is added to the solution. The solution is
_________.
(i) saturated
(ii) supersaturated
(iii) unsaturated
(iv) concentrated
5. Maximum amount of a solid solute that can be dissolved in a specified amount
of a given liquid solvent does not depend upon ____________.
(i) Temperature
(ii) Nature of solute
(iii) Pressure
(iv) Nature of solvent
6. Low concentration of oxygen in the blood and tissues of people living at high
altitude is due to ____________.
(i) low temperature
(ii) low atmospheric pressure
(iii) high atmospheric pressure
(iv) both low temperature and high atmospheric pressure
7. Considering the formation, breaking and strength of hydrogen bond, predict
which of the following mixtures will show a positive deviation from Raoult’s
law?
(i) Methanol and acetone.
(ii) Chloroform and acetone.
(iii) Nitric acid and water.
(iv) Phenol and aniline.
8. Colligative properties depend on ____________.
(i) the nature of the solute particles dissolved in solution.
(ii) the number of solute particles in solution.
(iii) the physical properties of the solute particles dissolved in solution.
(iv) the nature of solvent particles.
9. Which of the following aqueous solutions should have the highest boiling point?
(i) 1.0 M NaOH
(ii) 1.0 M Na2SO4
(iii) 1.0 M NH4NO3
(iv) 1.0 M KNO3
10. The unit of ebulioscopic constant is _______________.
(i) K kg mol–1 or K (molality)–1
(ii) mol kg K–1 or K–1(molality)
( iii) kg mol–1 K–1 or K–1(molality)–1
(iv) K mol kg–1 or K (molality)
11. In comparison to a 0.01 M solution of glucose, the depression in freezing point
of a 0.01 M MgCl2 solution is _____________.
(i) the same
(ii) about twice
(iii) about three times
(iv) about six times
12. An unripe mango placed in a concentrated salt solution to prepare pickle,
shrivels because _____________.
(i) it gains water due to osmosis.
(ii) it loses water due to reverse osmosis.
(iii) it gains water due to reverse osmosis.
(iv) it loses water due to osmosis.
13. At a given temperature, osmotic pressure of a concentrated solution of a
substance _____________.
(i) is higher than that at a dilute solution.
(ii) is lower than that of a dilute solution.
(iii) is same as that of a dilute solution.
(iv) cannot be compared with osmotic pressure of dilute solution.
14. Which of the following statements is false?
(i) Two different solutions of sucrose of same molality prepared in different
solvents will have the same depression in freezing point.
(ii) The osmotic pressure of a solution is given by the equation Π = CRT
( where C is the molarity of the solution).
(iii) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of
barium chloride, potassium chloride, acetic acid and sucrose is
BaCl2 > KCl > CH3COOH > sucrose.
(iv) According to Raoult’s law, the vapour pressure exerted by a volatile
component of a solution is directly proportional to its mole fraction in
the solution.
15. The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are
_____________.
(i) 2, 2 and 2
(ii) 2, 2 and 3
(iii) 1, 1 and 2
(iv) 1, 1 and 1
 16. Which of the following statements is false?
(i) Units of atmospheric pressure and osmotic pressure are the same.
(ii) In reverse osmosis, solvent molecules move through a semipermeable
membrane from a region of lower concentration of solute to a region of
higher concentration.
(iii) The value of molal depression constant depends on nature of solvent.
(iv) Relative lowering of vapour pressure, is a dimensionless quantity.
17. Value of Henry’s constant KH ____________.
(i) increases with increase in temperature.
(ii) decreases with increase in temperature.
(iii) remains constant.
(iv) first increases then decreases.
18. The value of Henry’s constant KH is _____________.
(i) greater for gases with higher solubility.
(ii) greater for gases with lower solubility.
(iii) constant for all gases.

(iv) not related to the solubility of gases
SOLID STATE EAMCET MCQ’S
1. Which of the following conditions favours the existence of a substance in the
solid state?
(i) High temperature
(ii) Low temperature
(iii) High thermal energy
(iv) Weak cohesive forces
2. Which of the following is not a characteristic of a crystalline solid?
(i) Definite and characteristic heat of fusion.
(ii) Isotropic nature.
(iii) A regular periodically repeated pattern of arrangement of constituent
particles in the entire crystal.
(iv) A true solid
3. Which of the following is an amorphous solid?
(i) Graphite (C)
(ii) Quartz glass (SiO2)
(iii) Chrome alum
(iv) Silicon carbide (SiC)
4. Which of the following is true about the value of refractive index of quartz glass?
(i) Same in all directions
(ii) Different in different directions
(iii) Cannot be measured
(iv) Always zero
5. Which of the following statement is not true about amorphous solids?
(i) On heating they may become crystalline at certain temperature.
(ii) They may become crystalline on keeping for long time.
(iii) Amorphous solids can be moulded by heating.
(iv) They are anisotropic in nature.
6. The sharp melting point of crystalline solids is due to ___________.
(i) a regular arrangement of constituent particles observed over a short
distance in the crystal lattice.
(ii) a regular arrangement of constituent particles observed over a long
distance in the crystal lattice.
(iii) same arrangement of constituent particles in different directions.
(iv) different arrangement of constituent particles in different directions.
7. Iodine molecules are held in the crystals lattice by ____________.
(i) london forces
(ii) dipole-dipole interactions
(iii) covalent bonds
(iv) coulombic forces
8. Which of the following is a network solid?
(i) SO2 (Solid)
(ii) I2
(iii) Diamond
(iv) H2O (Ice)
9. Which of the following solids is not an electrical conductor?
(A) Mg (s) (B) TiO (s) (C) I2 (s) (D) H2O (s)
(i) (A) only
(ii) (B) Only
(iii) (C) and (D)
(iv) (B), (C) and (D)
 10. Which of the following is not the characteristic of ionic solids?
(i) Very low value of electrical conductivity in the molten state.
(ii) Brittle nature.
(iii) Very strong forces of interactions.
(iv) Anisotropic nature.
11. Graphite is a good conductor of electricity due to the presence of __________.
(i) lone pair of electrons
(ii) free valence electrons
(iii) cations
(iv) anions
12. Which of the following oxides behaves as conductor or insulator depending
upon temperature?
(i) TiO
(ii) SiO2
(iii) TiO3
(iv) MgO
13. Which of the following oxides shows electrical properties like metals?
(i) SiO2
(ii) MgO
(iii) SO2(s)
(iv) CrO2
14. The lattice site in a pure crystal cannot be occupied by _________.
(i) molecule
(ii) ion
(iii) electron
(iv) atom
15. Graphite cannot be classified as __________.
(i) conducting solid
(ii) network solid
(iii) covalent solid
(iv) ionic solid
16. Cations are present in the interstitial sites in __________.
(i) Frenkel defect
(ii) Schottky defect
(iii) Vacancy defect
(iv) Metal deficiency defect
17. Schottky defect is observed in crystals when __________.
(i) some cations move from their lattice site to interstitial sites.
(ii) equal number of cations and anions are missing from the lattice.
(iii) some lattice sites are occupied by electrons.
(iv) some impurity is present in the lattice.
18. Which of the following is true about the charge acquired by p-type
semiconductors?
(i) positive
(ii) neutral
(iii) negative
(iv) depends on concentration of p impurity
19. To get a n-type semiconductor from silicon, it should be doped with a
substance with valence__________.
(i) 2
(ii) 1
(iii) 3
(iv) 5
20. The total number of tetrahedral voids in the face centred unit cell is __________.
(i) 6
(ii) 8
(iii) 10
(iv) 12
21. Which of the following point defects are shown by AgBr(s) crystals?
(A) Schottky defect (B) Frenkel defect
(C) Metal excess defect (D) Metal deficiency defect
(i) (A) and (B)
(ii) (C) and (D)
(iii) (A) and (C)
(iv) (B) and (D)
22. In which pair most efficient packing is present?
(i) hcp and bcc
(ii) hcp and ccp
(iii) bcc and ccp
(iv) bcc and simple cubic cell
23. Which of the following statement is not true about the hexagonal close
packing?
(i) The coordination number is 12.
(ii) It has 74% packing efficiency.
(iii) Tetrahedral voids of the second layer are covered by the spheres of the
third layer.
(iv) In this arrangement spheres of the fourth layer are exactly aligned with
those of the first layer.
24. In which of the following structures coordination number for cations and
anions in the packed structure will be same?
(i) Cl– ion form fcc lattice and Na+ ions occupy all octahedral voids of the
unit cell.
(ii) Ca2+ ions form fcc lattice and F – ions occupy all the eight tetrahedral
voids of the unit cell.
(iii) O2– ions form fcc lattice and Na+ ions occupy all the eight tetrahedral
voids of the unit cell.
(iv) S2– ions form fcc lattice and Zn2+ ions go into alternate tetrahedral voids
of the unit cell.
25. What is the coordination number in a square close packed structure in two
dimensions?
(i) 2
(ii) 3
(iii) 4
(iv) 6
26. Which kind of defects are introduced by doping?
(i) Dislocation defect
(ii) Schottky defect
(iii) Frenkel defects
(iv) Electronic defects
27. Silicon doped with electron-rich impurity forms ________.
(i) p-type semiconductor
(ii) n-type semiconductor
(iii) intrinsic semiconductor
(iv) insulator
28. Which of the following statements is not true?
(i) Paramagnetic substances are weakly attracted by magnetic field.
(ii) Ferromagnetic substances cannot be magnetised permanently.
(iii) The domains in antiferromagnetic substances are oppositely oriented
with respect to each other.
(iv) Pairing of electrons cancels their magnetic moment in the diamagnetic
substances.
29. Which of the following is not true about the ionic solids?
(i) Bigger ions form the close packed structure.
(ii) Smaller ions occupy either the tetrahedral or the octahedral voids
depending upon their size.
(iii) Occupation of all the voids is not necessary.
(iv) The fraction of octahedral or tetrahedral voids occupied depends upon
the radii of the ions occupying the voids.
30. A ferromagnetic substance becomes a permanent magnet when it is placed in
a magnetic field becuase ________.
(i) all the domains get oriented in the direction of magnetic field.
(ii) all the domains get oriented in the direction opposite to the direction of
magnetic field.
(iii) domains get oriented randomly.
(iv) domains are not affected by magnetic field.
31. The correct order of the packing efficiency in different types of unit cells is ________.
(i) fcc < bcc < simple cubic
(ii) fcc > bcc > simple cubic
(iii) fcc < bcc > simple cubic
(iv) bcc < fcc > simple cubic
32. Which of the following defects is also known as dislocation defect?
(i) Frenkel defect
(ii) Schottky defect
(iii) Non-stoichiometric defect
(iv) Simple interstitial defect
33. In the cubic close packing, the unit cell has ________.
(i) 4 tetrahedral voids each of which is shared by four adjacent unit cells.
(ii) 4 tetrahedral voids within the unit cell.
(iii) 8 tetrahedral voids each of the which is shared by four adjacent unit
cells.

(iv) 8 tetrahedral voids within the unit cells.

Thursday, July 3, 2014

AIR AROUND US                               
1. To walk through a waterlogged area, you usually shorten the length of your dress by folding it. Can be reversed?
Yes. This change can be reversed.
2.You accidentally dropped your favorite toy and brokeit.This is a change you did not want.Can this change be reverded?
No.This change cannot be reversed
3.Some changes are listed in the following table.For each change.write in the blank column,whether the change be reversed or not?
Sl.no
change
Can be reversed
(Yes/No)
1.
2.
3.
4.
5.
6.
The sawing of a piece of wood
The melting of ice candy
Dissolving sugar in water
The cooking of food
The ripening of a mango
Souring of milk
No
Yes
Yes
No
No
No

4.A drawing sheet change when you draw a picture on it.Can you reverse this change?
If the picture is drawn a pencil, then it can be erased, hence change can be reversed.But if picture is drawn with clours, the change cannot be reversed.
5.Give examples to explain the difference between change that can or cannot be reversed?
Some changes can be reversed,like
1)Filling water with glass
2)Opening/Closing door.
Other change cannot be reversed,like
1)Cording of milk
2) Ripening of fruit
6.A thin coating of a paste of plaster of paris is applied over the bandage on a fractured bone.It becomes hard on drying to keep the fractured bone immobilized.Can the change inPOP be reversed?
No.The change in POP cannot be reversed.
7.A bag of cement lying in the open gets wet due to rain during the night.The next day the sum shines brightly.Do you think the changes which have occurred in the cement could be reversed?
No.the changes which have occurred in the cement cannot  be reversed